Hey,

I'm looking for some BL where... uh.. i guess where the couple would be a younger brother (not shota) falls for the older brother friend or vise versa, so far I have a oneshot in Otodoke Shimasu and Sangen Tonari No Tooi Hito

Anyone know of any others?

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Relax, would you? We have seventy dollars and a pair of girls underpants. We're safe as kittens.

Boku wa Kimi no Tori ni Naritai is the only one I can think, hope it helps

Maybe Ore ni Koi Shite Dousunda?

Well, it's quite hard to find something comparable to Sangen Tonari No Tooi Hito, since it's one of my favorites, but spontaneously - How about Priceless Honey ("Replay") or Koakuma no Sanctuary (Vol. 1)? There are probably some more, so maybe this post will be edited later ... ^^"

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"It's like love is a bonus in your life. Even without it, I'm just fine. I don't feel like pointlessly searching for it. You don't have to make yourself unhappy." (Ookami Shoujo to Kuro Ouji)

"Why does it rain?" - "To create drama." (Drops (Andou Yuki))

Oaji wa Dou desu ka ch 6-7 Sakura Haijii
Ikura Nandemo Suki Sugiru ch 1-2
Kimi ga Koi ni Ochiru
Empty Heart
From 701 Goushitsu
and I suppose Junjou Romantica fits the theme too.

I'm certain I've read others that fit this theme as well so if I remember any other titles I'll add them.

Dare ga Omae wo Suki dato Itta, 1st story

Amayakana Toge - almost as you asked, except the love interest and the older brother were not exactly friends.

Suki no Mebae - this title was just posted in another thread, and though I haven't read it, it looks like it fits

Bump!

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K n e e l .... This is the difference between your and my eye-level.
Rai from Noblesse

Surprised no one has posted Rin! yet

Ijiwaru na Aitsu
Vibration Life